Product ID:3-CHLOROPEROXYBENZOIC ACID 27303-1
MSDS Date:03/14/1990
FSC:6810
NIIN:00N014218
MSDS Number: BKKVG

Info Phone: 414-273-3850

Cage: 60928

Telephone: 414-273-3850

Cage: 60928

PEROXYBENZOIC ACID, M-CHLORO- (3-CHLOROPEROXYBENZOIC ACID,

CAS: 937-14-4

RTECS: SD9480000

Fraction By Weight: 50-60%

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION,
INGESTION, OR SKIN ABSORPTION. CAUSES EYE AND SKIN IRRITATION.
MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY
TRACT.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS
AMOUNTS OF WATER. WASH CONTAMINATED CLOTHING BEFORE REUSE. INHAL:
REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION.
IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD. INGEST: CALL MD
IMMEDIATELY .

Extinguishing Media:WATER SPRAY. CO2, DRY CHEMICAL POWDER, ALCOHOL OR
POLYMER FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES.
STRONG OXIDIZER.
Unusual Fire/Explosion Hazard:MAY EXPLODE WHEN HEATED. THERMAL DECOMP
PRODUCTS MAY INCLUDE HCL AND PHOSGENE .

Spill Release Procedures:WEAR NIOSH/MSHA APPROVED SCBA, RUBBER BOOTS
AND HEAVY RUBBER GLOVES. SWEEP UP, PLACE IN A BAG AND HOLD FOR
WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL
SITE AFTER MATERIAL PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP TIGHTLY CLOSED. KEEP AWAY FROM
COMBUST MATLS, HEAT, SPARKS & OPEN FLAME. DO NOT STORE NEAR/NOR
ALLOW CONT W/CLTHG & OTHER COMBUST MATLS.
Other Precautions:AVOID CONTACT AND INHALATION. AVOID PROLONGED OR
REPEATED EXPOSURE. IRRITANT. REFRIGERATE. RAPID DECOMP TAKES PLACE
WHEN M- CHLOROPERBENZOIC ACID IS HEATED TO 100-104C. CONTAINS
3-CHLOROBENZOIC ACID, CHEM. ABSTRACTS REGISTRY (SEE SUPP DATA)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Protective Gloves:RUBBER GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:SAFETY SHOWER AND EYE BATH.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING,
DRINKING, SMOKING OR USING SANITARY FACILITIES .
Supplemental Safety and Health
OTHER PREC: NO. #535-80-8. NO SMOKING IN AREA OF USE. DO NOT USE IN THE
GENERAL VICINITY OF ARC WELDING, OPEN FLAME OR HOT SURFACES. HEAT
AND/OR UV RADIATION MAY CAUSE THE FORMATION OF HCL AND PHOSGEN E .

HCC:P1
Melt/Freeze Pt:M.P/F.P Text:156F,69C
Appearance and Odor:WHITE POWDER.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG BASES, STRONG REDUCING AGENTS & ORGANIC
MATERIALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES OF: CO AND CO2. HCL AND
PHOSGENE .

Waste Disposal Methods:PLEASE CONTACT THE TECHNICAL SERVICES
DEPARTMENT. BE SURE TO MENTION THE NAME, CATALOG NUMBER, AND THE
QUANTITY OF THE MATERIAL. DISPOSE OF IN ACCORDANCE WITH FEDERAL,
STATE, AND LOCAL LAWS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.